Hydrogen bonding to the electron accepting group controls the absorption spectrum of a push–pull stilbene adsorbed on amorphous silica

Author(s)

Dóra Vörös, Felix Proché, Leticia González, Sebastian Mai

Abstract

The photophysical and photochemical properties of push–pull photoswitches, such as stilbene derivatives, are very sensitive to their surroundings, allowing, e.g., for the control of the spectral properties or alternatively for probing the molecular environment. Here, we investigate how various adsorption motifs of 4-(N, N-Dimethylamino)-4’-nitrostilbene (DANS) on an amorphous glass surface influence its absorption spectra. Particular attention is given to the prominent first bright charge transfer state and the factors governing these modifications. The absorption spectra is simulated using time-dependent density functional theory on a large set of adsorption geometries that exhibit different kinds of molecule–surface interactions. We find that C–H⋯O interactions of the methyl or phenyl moieties with the glass affect the spectrum only marginally, whereas the dispersion interaction of the π system with the surface tends to diminish the intensity of the first absorption band. Moreover, an enhancement of the push–pull properties of DANS and a significant redshift occur whenever O–H⋯O hydrogen bonds with the NO₂ group are present, whereas a hydrogen bond O–H⋯N to the NMe₂ group results in a blueshift. (Figure presented.)

Organisation(s)

Department of Theoretical Chemistry, Research Platform Accelerating Photoreaction Discovery

External organisation(s)

Vienna Doctoral School in Chemistry (DoSChem)

Journal

Communications Physics

Volume

7

ISSN

2399-3650

DOI

https://doi.org/10.1038/s42005-024-01755-x

Publication date

12-2024

Peer reviewed

Yes

Austrian Fields of Science 2012

103006 Chemical physics, 104022 Theoretical chemistry

ASJC Scopus subject areas

General Physics and Astronomy

Portal url

https://ucrisportal.univie.ac.at/en/publications/63b12d69-9e25-4402-a06f-5bb706e910cc